Nanoparticle catalysed oxidation of sulfides to sulfones by in situ generated H2O2 in supercritical carbon dioxide/water biphasic medium.
نویسندگان
چکیده
In a one-pot reaction, hydrogen peroxide generated from H(2) and O(2) on a Pd catalyst was utilised as oxidant for the TiO(2) catalyzed conversion of a sulfide to a sulfone. This transformation, where two different nanoparticle catalysts were employed in a supercritical carbon dioxide/water biphasic system, demonstrates the potential of compartmentalising catalytic processes in consecutive reactions.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 36 شماره
صفحات -
تاریخ انتشار 2010